In this study, effects of environmental temperature on susceptibility to sulfide stress cracking ssca type of hydrogen embrittlement he occurring in sour environmentsof low alloy steels were investigated from the perspective of hydrogen entry, absorption, and accumulation. Sulfide stress cracking ssc has been regarded as a source of major failures in the oil and gas industry, causing significant economic and human losses. Technical report development for material and application. Sulfide stress cracking mostly occurs in very highly acidic environments. The wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of khangirans sour gas wells. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour. Steel castings handbook supplement 8 high alloy data. Sulfide stress cracking of nickelcontaining lowalloy. The article also introduces a quantitative criterion to determine the maximum allowable defect size based on fracture mechanics principles. The susceptibility to sscc depends on the microstructural characteristics of the material.
Pdf a discussion covers the nace international standard mr0175. Sulfide stress crackingresistant drill pipe addresses h2s. Foreword this standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. Hydrogen sulphide corrosion cracking of steel corrosion. This article describes current industry practices to catalog features observed after sulfide stress cracking testing. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas.
The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Highstrength steels with improved sulfide stress cracking resistance. It is an environmental cracking mechanism that can initiate on the surface of high strength alloy steels or carbon steels containing localized areas of high hardness stress. Concentration cells can form in the deposits of corrosion products, leading to localized corrosion. Dec 21, 2017 in other words, it can support a stress of 80,000 psi with an elongation of less than 0. Tcr engineering mumbai corrosion testing, nace, astm.
After several sulfide stresscracking failures occurred in texas in the mid1970s. Welding residual stress generation and metallurgical change by fusion welding process increase the cracking driving force and reduce the resistance of brittle fracture as well as environmental fracture. Typically these conditions occur in oil and gas extraction, predominantly offshore. Both references 1 and 2 underline the detrimental e. Is sulfide stress cracking an anodic or a cathodic process. Sulfide stress cracking of pipelinecase history onepetro.
You cant catch cracking in progress, the way you can catch metalremoval corrosion by monitoring thicknesses. Dec 19, 2019 ssc is a form of spontaneous brittle breakdown in occurring in highstrength alloys and steels when it comes in contact with humid hydrogen sulfide as well as sulfidic atmospheres. Ssc abbreviation stands for sulfide stress cracking. It is appreciated that a material used in an h2s corrosive medium can suffer sulfide stress cracking ssc, a form of hydrogen embrittlement cracking occurring in h2s environments. This type of cracking is also known as underbead cracking, toe cracking, or delayed cracking. Sulfide stress corrosion cracking sscc in crude oil field environment including hydrogen sulfide h 2 s has been recognized as a materials failure mechanism. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. But, the presence of h 2 s in well fluids imposes severe restrictions on the use of tubular goods due to sulfide stress cracking phenomenon 2. Test frames for applying cyclic loads with the measurement of crack propagation rates.
In combination with increased temperatures and pressure in environments containing chloride, sulfide stress cracking ssc can occur. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. Standard test method laboratory testing of metals for. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. When oxygen is absent, sulfatereducing bacteria are active and produce hydrogen sulfide causing sulfide stress cracking. Standard material requirements materials resistant to. In this chapter the terms eac and scc are generally interchangeable. In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. Since the first discovery of stress corrosion cracking scc on the exterior surface of a buried high. Reliability of dissimilar metal welds subjected to sulfide.
Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Mar 28, 2011 weishan huang, jingli luo, hani henein and josiah jordan, sulfide stress cracking assessment of lowalloy l80 casing steel in h 2 s environment, anticorrosion methods and materials, 10. Investigators, after discarding embrittlement as a. Sulfide stress cracking ssc ssc is a form of hydrogen stress cracking hsc. Sulfide stress cracking and corrosion fatigue of steels. Microbial corrosion, commonly referred to as microbiologically influenced corrosion mic is caused by microorganisms.
Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. Stress corrosion crack scc is a crack which may be intergranular or transgranular depending on the material, resulting from the combined action of corrosion and stress, either external applied or internal residual. Specialized stress corrosion cracking testing capabilities. Summary sulfide stress cracking ssc is just one of several forms of hydrogen. Processes or conditions involving wet hydrogen sulfide, i. Hydrogen assisted cracking of high strength alloys richard. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Sulfide stress cracking ssc vs hydrogen induced cracking hlc.
This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress cracking nace mr01752002, mr0175iso 15156. The influence of microstructure and inclusion on the susceptibility to stress oriented hydrogen induced cracking, sohic, or type i sulfide stress cracking, ssc, was investigated for two kinds of. Types of corrosion american galvanizers association. Materials for use in h2scontaining environments in oil and gas production 1. Stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Reliability of dissimilar metal welds subjected to sulfide stress cracking vol. Crolet points out that the combination of stress and hydrogen initiates the formation of local hic and then the formation of sohic. Wet hydrogen sulfide h2s cracking inspectioneering. Hydrogen sulfide stress corrosion cracking in materials for. Resistance to sulfide stress cracking natural gas and oil inherently contain a certain amount of hydrogen sulphide h 2 s. Effect of testing temperature on sulfide stress cracking.
Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Stress corrosion cracking can be defined as the interaction of a tensile stress and an aqueous environment acting on a susceptible metallic surface to initiate and propagate cracks. Biaxial stress corrosion cracking frames capable of conducting testing in aggressive environments, such as brines with co 2 and h 2 s. Hydrogen assisted cracking of high strength alloys richard p. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Aug 14, 20 carneiro r a, ratnapuli r c and lins v f c l. February 19, 2017 by mariano iannuzzi in a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. A95 stainless steel is designed to combine improved resistance to stress corrosion cracking including sulfide stress corrosion crackingpitting, crevice corrosion and high strength when compared with other stainless alloys. Pdf the wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking.
Pdf sulfide stress corrosion cracking and hydrogen induced. Uniform and non uniform thinning of pipe walls due to metal removal corrosion was controlled by the development of. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. Sulfide stress cracking an overview sciencedirect topics. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Sulfide stress cracking ssc is just one of several forms of hydrogen. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6.
This part of iso 15156 addresses all mechanisms of cracking that can be caused by h2s, including sulfide stress cracking, stress corrosion cracking, hydrogen. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. When oxygen is present, some bacteria may directly oxidize iron to iron oxides and hydroxides. Standard material requirements sulfide stress cracking. Sour service is a environment containing water and h2s hydrogen sulfide with pressure of 50ppm if the presence of hydrogen sulfide i. During investigation many cracks were observed on the inner surface of the valve body grown from the surface pits. In this environment, not only is hydrogen sulfide stress cracking a concern, but the presence of. Sulfide stress corrosion cracking ssc is a form of hydrogen embrittlement cracking which occurs when a susceptible material is exposed to a corrosive environment containing water and h2s at a critical level of applied or residual tensile stress. Among the most prone to sulfide stress cracking include valve trim, blowout preventer hard parts and tool joints. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur.
Home which alloy is best to resist sulfide stress cracking and stress. Laboratory testing of metals for resistance to sulfide stress. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Usually, the resistance to ssc is evaluated using nace standard tm01771, and in particular the tensile test method a. Oct 24, 20 sulfide stress cracking resistant drill pipe addresses h2s challenges.
The limit of sour service ss grades regarding sulfide stress cracking ssc resistance is defined by ansi nace mr0175 iso 15156. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. This part of iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stress oriented hydrogeninduced cracking, soft zone cracking, and galvanically induced hydrogen stress cracking. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Ian sutton, in plant design and operations second edition, 2017. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfide stress cracking resistance of 95 and 110 ksi octg sour. Ansinace mr0175iso 15156, petroleum and natural gas industries. Other types of material damage include hydrogen blistering, hydrogeninduced cracking hic, and stressoriented hydrogeninduced cracking sohic, which are. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production.
Which alloy is best to resist sulfide stress cracking and stress corrosion cracking. Sulfide stress cracking nace mr01752002, mr0175iso. Sulfide stress cracking oil and gas pipelines wiley online library. Nace standard tm01772005 laboratory testing of metals. This part of ansinace mr0175iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stress oriented hydrogeninduced cracking, soft zone cracking, and galvanically induced hydrogen stress cracking. Abstract it has been found that higher yield strength stainless steel 410 is generally more susceptible to sulfide stress cracking, but complicating factor such as microstructure can have significant effect in this susceptibility too. Sulphide stress cracking can be especially troublesome as. Mar 27, 2014 the valve body alloy was a216wcc cast carbon steel. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body.
Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. It is also interesting to remark that nace standard mr 0103, materials resistant to sulfide stress cracking in corrosive petroleum refining environments ansinace, 2012, which was adapted from iso 15156 to cover sour petroleum refining and related processing environments containing h 2 s, does not impose any restriction in terms of nickel content. The laboratory critical constants were found to be lower. Coilgard inhibitor can be applied as a batch treatment or by placement in the treating fluid. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. Pdf detecting sulfide stress cracking and applying nace mr0175. The opinions and conclusions stated are those of the author and may or may not be those of the laboratory. Sulfide stress cracking oil and gas pipelines wiley. Scavenging of h 2s is not necessary for it to function. Sulfide stress cracking ssc was first identified and the mechanism outlined in the 1940s after several failures of oil and gas systems in texas and canada. Coilgard inhibitor protects against cracking corrosion that can cause catastrophic failures in stressed steels, such as coiled tubing. Pdf stress corrosion cracking and hydrogen cracking. It looks at the various forms of cracking, the nature of cracking, its causes and how it is prevented. Induced cracking and sulfide stress cracking uhlig.
Sulfide stress corrossion cracking resistant metallic materials for oil. Nace standard tm0177, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments 1. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Corrosionpedia what is sulfide stress cracking ssc. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking.
A lower carbon content, as in grade ca6nm class b, permits heat treating to a lower maximum hardness and str ength whci h results in improved corrosion resistance, particularly resistance to sulfide stress corrosion cracking. The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi. H 2 s can cause sulfide stress cracking of stainless steels. Micro alloyed pipeline steels are commonly used in the petroleum industry for transport applications 1. Pdf sulfide stress corrosion cracking and hydrogen. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Sulfide stress cracking how is sulfide stress cracking. Stress corrosion cracking tests using doublecantileverbeam specimens ajit roy october 25,1996 this is an informal report intended primarily for internal or limited external. The high resistance of sandvik saf 2205 is shown in the figure by the fact that very high stresses, about 1. Sulfide stress cracking of stainless steel 410 in sour. What is the abbreviation for sulfide stress cracking. Sulfide stress corrosion cracking of steels corrosion. Stressoriented hydrogeninduced cracking of l360qs steel. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by.
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